Safety Summary. Urea
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1 Novomoskovskiy Azot 10 Svyazi St., Novomoskovsk, Tula Region, , Russia Safety Summary Global Product Strategy (GPS) according to the recommendations of International Council of Chemical Associations (ICCA) as the fulfillment of the obligations under the Strategic Approach to International Chemicals Management (SAICM) of United Nations (UN). Urea This safety summary is provided within the scope of ICCA Global Product Strategy (GPS) to provide to the general public. GPS safety summary includes explanations on the possible chemical hazards and/or exposure scenarios, as well as information on safe handling and risk management. This summary is not intended to provide technical information on emergency actions, medical information or information on treatment in case of exposure. 1. General Information Producer: Novomoskovskiy Azot (NAK Azot) Address: 10 Svyazi St., Novomoskovsk, Tula Region, , Russia Tel.: +7 (48762) , ext: Fax: +7 (48762) , ext Novomoskovsk@eurochem.ru 2. Substance Identification Trade name Urea Chemical Name Urea CASNo ECNo Molecular formula CH 4 N 2 O Structural formula
2 3. Product Description and Uses Urea is mainly used as raw material for industry and nitrogen fertilizer. Main components of product. Chemical name Concentration, % wt CAS EC / Registration number Classified GHS Urea / Not classified Biuret 1, Not classified Water 0, Not classified There are two grades of urea (according to GOST ): Grade A for industrial use Grade B for crop and livestock farming and retail trade Main technical characteristics for Grade A (according to GOST ): Name Standard Prime quality Weight percentage of N calculated on a dry basis, %, no less than 46,3 46,2 Weight percentage of Biuret, %, no more than 0,6 1,4 Weight percentage of free ammonia, %, no more than: for crystalline urea for granulose urea Weight percentage of water, %, no more than: for hygroscopic water for common water 0,01 0,02 0,6 1 st quality 0,01 0,03 0,6 Page 2 of 9
3 Main technical characteristics for Grade B (according to GOST ): Name Standard for crop farming for retail trade Prime quality 1 st quality 2 nd quality Appearance White or slightly colored granules (grains) or crystals Weight percentage of N calculated on a dry basis, %, no less than 46,2 46,2 46,2 46,2 Weight percentage of Biuret, %, no more than 1,4 1,4 1,4 1,5 Weight percentage of water, %, no more than: for hygroscopic water for common water Granulometric composition, %: Weight percentage of granules, size, mm: 1 4, no less than 2 4, no less than < 1, no more than Sieve residue, 6 mm Static load strength of granules, МPа (kg/сm 2 ), no less than or calculated on 1 granule, N, (kgf), no less than 0, None 1,4 (14) 7(0,7) 0, None 1,2(12) 5(0,5) 0, None 1,2(12) 3 () 4. Physical/Chemical Properties Physical state Granulous Colour No data available Odor No data available Melting point 134 С Boiling point Explosive properties Flammability Not flammable Oxidizing properties No oxidizing properties Molecular Weight g/mol ph Density Poured density 0,670,80 g/сm 3 Vapor pressure 0,002 kpa at 25 C Water solubility 624 g/l at 20 C Partition coefficient: noctanol/water 1.73 at 20 C 5. Health Information 5.1 DNEL (Derived NoEffect Level)/DMEL (Derived Minimal Effect Level) for workers Page 3 of 9
4 Inhalation acute systemic effects, mg/m 3 : 292 Inhalation acute local effects: no data available Inhalation longterm systemic effects, mg/m 3 : 292 Inhalation longterm local effects: no data available Dermal acute systemic effects, mg/kg bw day: 580 Dermal acute local effects: no data available Dermal longterm systemic effects, mg/kg bw day: 580 Dermal longterm local effects: no data available Oral acute systemic effects: no data available Oral acute local effects: no data available Oral longterm systemic effects: no data available Oral longterm local effects: no data available DNEL (Derived NoEffect Level)/DMEL (Derived Minimal Effect Level) for consumers Inhalation acute systemic effects, mg/m 3 : 125 Inhalation acute local effects: no data available Inhalation longterm systemic effects, mg/m 3 : 125 Inhalation longterm local effects: no data available Dermal acute systemic effects, mg/kg bw day: 580 Dermal acute local effects: no data available Dermal longterm systemic effects: 580 Dermal longterm local effects: no data available Oral acute systemic effects, mg/kg bw day: 42 Oral acute local effects: no data available Oral longterm systemic effects, mg/kg bw day: 42 Oral longterm local effects: no data available 5.2 Toxicity estimate Acute oral toxicity LD 50 (rats) mg/kg: Acute dermal toxicity: no data available Acute inhalation toxicity: no data available Chronic inhalation toxicity: no data available Chronic dermal toxicity: no data available Chronic oral toxicity: no data available 5.3 Irritation/Corrosivity/Sensitization Irritation/corrosion (eyes/skin): no effect Sensitization (skin/respiratory tract): no effect 5.4 CMReffects Mutagenicity: no mutagenic effect Carcinogenicity: no carcinogenic effect Reproductive toxicity: not toxic 5.5 Specific targetorgan toxicity Specific targetorgan Central & peripheral nervous system, respiratory system, liver, kidneys. OralSTOTrepeated exposure (subacute/subchronic) LOAEL (subchronic, rats, 12 months): 2250 mg/kg 6. Environmental information 6.1 Predicted No Effect Concentration (PNEC) Page 4 of 9
5 PNEC aqua freshwater, mg/l: 0.47 PNEC aqua marine water, mg/l: 0,047 PNEC aqua intermittent releases: no data available PNEC sediment freshwater: no data available PNEC sediment marine water: no data available PNEC soil: no data available PNEC STP: no data available 6.2 Toxicity value Shortterm toxicity to fish LC 50 (Leuciscus idus), 96 h: > mg/l Longterm toxicity to fish NOEC (Gambusia affinis), 1 wk: 200 mg/l Shortterm toxicity to aquatic invertebrates EC 50 (Daphnia), 24 h: > mg/l Longterm toxicity to aquatic invertebrates: no data available Toxicity to aquatic algae NOEC (Euglena gracilis), 24 h: 10.5 g/l Toxicity to microorganisms EC 50 (Toxicity Threshold), 16 h: > mg/l Toxicity to aquatic algae and cyanobacteria NOEC (Microcystis aeruginosa), 8 days: 47 mg/l 6.3 Environmental fate Phototransformation in air: no data available Phototransformation in water: no data available Phototransformation in soil: no data available Hydrolysis: no data available Biodegradation in water: screening tests: easily biodegradable Biodegradation in water and sediment: simulation tests: easily biodegradable Biodegradation in soil: easily biodegradable Bioaccumulation: aquatic / sediment: no data available Bioaccumulation: terrestrial: no data available Adsorption / desorption: no data available Henry's Law constant: no data available PBT and vpvb assessment: Not a PBT/vPvB substance 7. Exposure Assessment See section Recommendations on Risk Management Closed manufacturing processes (if necessary), performance forcedair or local exhaust ventilation at the work zone, use of personal protection equipment. Minimization of quantity of exposed workers. Use of special dispensers and pumps designed to prevent splashes / spills. Effective removal of contaminants. Minimization of manual phases. Avoidance of contact with contaminated tools and objects. Regular cleaning of equipment and work area. Verification of the appropriate use of risk management measures. Ensure high levels of personal hygiene. Inform consumers through labeling. 9. Classification and labelling 9.1 Classification Not classified 9.2 Labelling Page 5 of 9
6 10. Registration information Urea Registration Number: In the Product Safety Summary for risk calculations the following Exposure scenarios are used: Identifiers ES1 M1 ES2 F1 ES3 IW1 ES4 IW2 Market Sector Titles of exposure scenarios and the related contributing scenarios Manufacture Manufacture Manufacture (ERC 1) Worker contributing scenario (PROC 1) Worker contributing scenario (PROC 2) Worker contributing scenario (PROC 3) Worker contributing scenario (PROC 8b) Worker contributing scenario (PROC 9) Worker contributing scenario (PROC 15) Formulation Formulation Formulation (ERC 2) Worker contributing scenario (PROC 1) Worker contributing scenario (PROC 2) Worker contributing scenario (PROC 3) Worker contributing scenario (PROC 4) Worker contributing scenario (PROC 5) Worker contributing scenario (PROC 7) Worker contributing scenario (PROC 8a) Worker contributing scenario (PROC 8b) Worker contributing scenario (PROC 9) Worker contributing scenario (PROC 10) Worker contributing scenario (PROC 11) Worker contributing scenario (PROC 15) Use at industrial site Use at industrial site Use at industrial site (ERC 4) Worker contributing scenario (PROC 1) Worker contributing scenario (PROC 2) Worker contributing scenario (PROC 3) Worker contributing scenario (PROC 4) Worker contributing scenario (PROC 5) Worker contributing scenario (PROC 7) Worker contributing scenario (PROC 8a) Worker contributing scenario (PROC 8b) Worker contributing scenario (PROC 9) Worker contributing scenario (PROC 10) Worker contributing scenario (PROC 11) Worker contributing scenario (PROC 15) Use at industrial site Use at industrial site Use at industrial site (ERC 6a) Page 6 of 9
7 Identifiers ES5 IW3 ES6 PW1 ES7 PW2 ES8 C1 ES9 C2 Market Sector Titles of exposure scenarios and the related contributing scenarios Worker contributing scenario (PROC 1) Worker contributing scenario (PROC 2) Worker contributing scenario (PROC 3) Worker contributing scenario (PROC 4) Worker contributing scenario (PROC 5) Worker contributing scenario (PROC 7) Worker contributing scenario (PROC 8a) Worker contributing scenario (PROC 8b) Worker contributing scenario (PROC 9) Worker contributing scenario (PROC 10) Worker contributing scenario (PROC 11) Worker contributing scenario (PROC 15) Use at industrial site Use at industrial site Use at industrial site (ERC 6d) Worker contributing scenario (PROC 1) Worker contributing scenario (PROC 2) Worker contributing scenario (PROC 3) Worker contributing scenario (PROC 4) Worker contributing scenario (PROC 5) Worker contributing scenario (PROC 7) Worker contributing scenario (PROC 8a) Worker contributing scenario (PROC 8b) Worker contributing scenario (PROC 9) Worker contributing scenario (PROC 10) Worker contributing scenario (PROC 11) Worker contributing scenario (PROC 15) Use by professional worker Use by professional worker Use by professional worker (ERC 8c) Worker contributing scenario (PROC 1) Worker contributing scenario (PROC 2) Worker contributing scenario (PROC 3) Use by professional worker Use by professional worker Use by professional worker (ERC 8f) Worker contributing scenario (PROC 1) Worker contributing scenario (PROC 2) Worker contributing scenario (PROC 3) Consumer Use Consumer Use Consumer Use (ERC 8e) Consumer contributing scenario (PC 12) Related subsequent service life: ES11; ES12 Consumer Use Consumer Use Consumer Use (ERC 8f) Consumer contributing scenario (PC 1) Consumer contributing scenario (PC 3) Consumer contributing scenario (PC 8) Consumer contributing scenario (PC 9a) Consumer contributing scenario (PC 9b) Consumer contributing scenario (PC 9c) Consumer contributing scenario (PC 13) Page 7 of 9
8 Identifiers ES10 C3 ES11 SLC1 ES12 SLC2 Market Sector Titles of exposure scenarios and the related contributing scenarios Consumer contributing scenario (PC 15) Consumer contributing scenario (PC 18) Consumer contributing scenario (PC 21) Consumer contributing scenario (PC 23) Consumer contributing scenario (PC 31) Consumer contributing scenario (PC 32) Consumer contributing scenario (PC 35) Consumer contributing scenario (PC 37) Consumer contributing scenario (PC 39) Related subsequent service life: ES11; ES12 Consumer Use Consumer Use Consumer Use (ERC 8d) Consumer contributing scenario (PC 1) Consumer contributing scenario (PC 3) Consumer contributing scenario (PC 8) Consumer contributing scenario (PC 9a) Consumer contributing scenario (PC 9b) Consumer contributing scenario (PC 9c) Consumer contributing scenario (PC 13) Consumer contributing scenario (PC 15) Consumer contributing scenario (PC 18) Consumer contributing scenario (PC 21) Consumer contributing scenario (PC 23) Consumer contributing scenario (PC 31) Consumer contributing scenario (PC 32) Consumer contributing scenario (PC 35) Consumer contributing scenario (PC 37) Consumer contributing scenario (PC 39) Related subsequent service life: ES11; ES12 Service life (consumers) Service life (consumers) Service life (consumers) (ERC 11a) Consumer service life contributing scenario (AC 8) Consumer service life contributing scenario (AC 11) Service life (consumers) Service life (consumers) Service life (consumers) (ERC 10a) Consumer service life contributing scenario (AC 0) GPS safety risk calculations performed for production, processing, use and disposal of urea and when exposed to the consumer and the environment (in accordance with the ECHA Guidelines on Safety Assessment). The analysis shows that risks could be adequately controlled through the use of standardized technical, organizational measures, which are designed and operated by NAK Azot. Page 8 of 9
9 12. Contact information For more information on the matter, please contact: or visit: 13. Date of issue 15Dec2015 Notes For more information on first aid measures, fire fighting, prevention and prevention and prevention and elimination of accidents and emergency situations and their consequences, recycling, safe use and transportation and storage rules, refer to the Safety Data Sheet (SDS) for this chemical or chemical product. While the data and information contained herein are presented in good faith and believed to be accurate at the date of printing, it is provided for your guidance only and may be revised in the future. No warranties of any kind, either express or implied, of merchantability, fitness for a particular purpose or of any other nature are made regarding the data or information provided. Further, the Company assumes no obligation or liability whatsoever resulting from use of or reliance on the data and information given. The Company makes no commitment to update or correct any information that appears on the Internet. Page 9 of 9
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