Investor Teleconference Presentation Third Quarter October 25, 2006

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Investor Teleconference Presentation October 25,

10/25/06 2 Earnings Teleconference Forward Looking Statements This document contains forward-looking statements within the meaning of the Private Securities Litigation Reform Act of 1995. These statements are based on management s reasonable expectations and assumptions as of the date the statements are made but involve risks and uncertainties. These risks and uncertainties include, without limitation: the performance of stock markets generally; developments in worldwide and national economies and other international events and circumstances; changes in foreign currencies and in interest rates; the cost and availability of electric power, natural gas and other raw materials; the ability to achieve price increases to offset cost increases; catastrophic events; the ability to attract, hire, and retain qualified personnel; the impact of changes in financial accounting standards; the impact of tax and other legislation and government regulation in jurisdictions in which the company operates; the cost and outcomes of litigation and regulatory agency actions; continued timely development and market acceptance of new products and applications; the impact of competitive products and pricing; future financial and operating performance of major customers and industries served; and the effectiveness and speed of integrating new acquisitions into the business. These risks and uncertainties may cause actual future results or circumstances to differ materially from the projections or estimates contained in the forward-looking statements. The company assumes no obligation to update or provide revisions to any forward-looking statement in response to changing circumstances. The above listed risks and uncertainties are further described in Item 1A (Risk Factors) in the company s latest Annual Report on Form 10-K filed with the SEC which should be reviewed carefully. Please consider the company s forward-looking statements in light of those risks.

Earnings Teleconference Results (1) ($MM) Second 2005 ( ² ) YOY Q3 vs Q2 Sales Growth +11% +1% Sales $2,099 $2,076 $1,890 Operating Profit $ 392 $ 382 $ 307 Operating Margin 18.7% 18.4% 16.2% Net Income $ 247 $ 247 $ 193 Diluted EPS $ 0.75 $ 0.75 $ 0.59 After-Tax ROC 14.3% 14.5% 12.5% Volume +6% +1% Price +4% 0% Currency +2% +1% Natural Gas - 1% 0% Acquisitions 0% - 1% 3Q 06 includes gain on divestitures + $14MM Operating Profit - ($11MM) Taxes + $ 3MM Net Income + $ 0.01 EPS (1) Includes Non-GAAP measures, see Appendix. (2) 2005 quarter is shown on a comparable basis, adjusted to include stock option expense, 2 cents per diluted share; and exclude a $92 million tax charge, 28 cents per diluted share 10/25/06 3

Earnings Teleconference North America (1) ($MM) Second 2005 Growth in on-site and merchant gas volumes across all major end markets Strong packaged gases, PDI +14% YOY Sales $1,187 $1,158 $1,087 Segment OP $ 204 $ 215 $ 159 Operating Margin 17.2% 18.6% 14.6% YOY Q3 vs Q2 Sales Growth +9% +3% Volume +5% +2% Price +5% +1% Natural Gas - 2% 0% Currency +1% 0% Pricing initiatives continuing to offset higher power costs Productivity savings improving margins High level of new business development activity Key Indicators YOY On-Site Volume +6% Merchant Volume +3% LIN/LOX Volume +5% LIN/LOX Price Index +8% (1) 2005 quarter is shown on a comparable basis, adjusted to include stock option expense. Non-GAAP measure, see Appendix. 10/25/06 4

10/25/06 5 Earnings Teleconference North American Volumes 125 120 115 110 Index 105 100 95 90 85 1Q01 3Q01 1Q02 3Q02 1Q03 3Q03 1Q04 3Q04 1Q05 3Q05 1Q06 3Q06 Merchant On-Site Volumes not days adjusted

10/25/06 6 Earnings Teleconference North America - Packaged Gas Sales Per Day 4,500 $ 000 2,000 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2004A 2005A A Industrial sales only

Earnings Teleconference Europe (1) ($MM) Sales $293 $296 $258 Segment OP $ 69 $ 65 $ 62 Operating Margin 23.5% 22.0% 24.0% YOY Second 2005 Q3 vs Q2 Sales Growth +14% -1% Volume +6% - 4% Price +4% +1% Currency +4% +2% Strong sales growth to electronics market Strong healthcare sales in Spain and Italy Operating profit includes $5MM gain from divestiture in Turkey Difficult pricing environment unable to fully offset significantly higher power costs On track for $30MM productivity savings in (1) 2005 quarter is shown on a comparable basis, adjusted to include stock option expense. Non-GAAP measure, see Appendix. 10/25/06 7

Earnings Teleconference South America (1) ($MM) Sales $340 $340 $292 Segment OP $ 69 $ 58 $ 51 Operating Margin 20.3% 17.1% 17.5% YOY Second Q3 vs Q2 Sales Growth +16% 0% Volume +7% +5% Price +1% - 1% Currency +6% 0% Equipment Sale +2% - 4% 2005 Sales growth due to three plant start-ups and improved volumes CST LNG Owens Corning Q206 included $22MM plant sale Higher sales to metals, energy and healthcare markets Margin improvement from higher volumes and productivity improvements Stable currency, trade surplus in Brazil (1) 2005 quarter is shown on a comparable basis, adjusted to include stock option expense. Non-GAAP measure, see Appendix. 10/25/06 8

Earnings Teleconference Asia (1) ($MM) Sales $165 $155 $136 Segment OP $ 27 $ 28 $ 23 Operating Margin 16.4% 18.1% 16.9% YOY Second Q3 vs Q2 Sales Growth +21% +6% 2005 Strong sales growth in Korea and China Electronics sales +37% YOY Higher sales across the region to chemicals, metals, electronics and food and beverage High level of business development activity in India and China Volume +20% +5% Price +2% +2% Currency +2% - 1% Equipment Sale - 3% 0% (1) 2005 quarter is shown on a comparable basis, adjusted to include stock option expense. Non-GAAP measure, see Appendix. 10/25/06 9

Earnings Teleconference Surface Technologies (1) ($MM) Second 2005 Sales $114 $127 $117 Segment OP $ 23 $ 16 $ 12 Operating Margin 20.2% 12.6% 10.3% Sales +9% ex-divestiture and currency Sales impact of aviation repair divestiture (-$17MM). Segment OP includes $7MM gain on sale Strong coatings demand from aerospace, power and energy markets Margin improvement from higher volumes and fixed cost control (1) 2005 quarter is shown on a comparable basis, adjusted to include stock option expense. Non-GAAP measure, see Appendix. 10/25/06 10

Earnings Teleconference Global End-Market Trends Q3 YOY Sales Growth Energy ( ¹ ) +16% Refinery hydrogen, gas well fracturing and CNG/LNG in Brazil Electronics Chemicals Metals Manufacturing Healthcare +33% +7% +23% +16% +5% Growth in materials science, increased semiconductor production Strong comparables due to Katrina New projects in Asia and South America, higher volumes in US and Europe Strong global demand for infrastructure and machinery Organic growth offset by price reductions Aerospace ( ² ) Food and Bev. +19% +10% Strong OEM engine orders in PST Strong season for beverage carbonation tight supply situation (1) Excluding natural gas pass-through (2) Excluding effect of divestiture 10/25/06 11

10/25/06 12 Earnings Teleconference Financial Outlook Fourth Full Year YOY sales growth of 6% to 9% Sales comparisons will be negatively impacted by last year s high natural gas prices (and consequently lower natural gas pass-through this year) particularly in October Diluted EPS in the range of $0.75 to $0.78 Includes ($0.02) stock option expense impact YOY sales growth of about 10% Diluted EPS in the range of $2.93 to $2.96 Includes ($0.08) stock option expense impact Tax rate about 26-27% CAPEX in the area of $1.05 Billion to $1.10 Billion

10/25/06 13 Earnings Teleconference APPENDIX

10/25/06 14 Earnings Teleconference Non-GAAP Measures ($MM) PRAXAIR, INC. AND SUBSIDIARIES APPENDIX NON-GAAP MEASURES (Dollar amounts in millions) (UNAUDITED) Definitions of the following non-gaap measures may not be comparable to similar definitions used by other companies. Praxair believes that (i) its debt-to-capital ratio is appropriate for measuring its financial leverage; (ii) its after-tax return on invested capital ratio is an appropriate measure for judging performance as it reflects the approximate after-tax profit earned as a percentage of investments by all parties in the business (debt, minority interests and shareholders equity) and the adjusted ROC amount will help investors understand underlying performance on a comparable basis; and (iii) operating profit, net income and diluted EPS amounts that include pro-forma stock option expense in 2005 periods, help investors understand underlying performance on a comparable basis. 2005 Q3 Q2 Q1 Q4 Q3 Q2 Q1 Total Capital Total debt $ 3,174 $ 3,454 $ 3,408 $ 3,447 $ 3,272 $ 3,327 $ 3,449 Minority interests 209 203 207 202 225 225 221 Shareholders' equity 4,494 4,269 4,125 3,902 3,873 3,821 3,651 Total Capital $ 7,877 $ 7,926 $ 7,740 $ 7,551 $ 7,370 $ 7,373 $ 7,321 Debt-to-Capital Ratio 40.3% 43.6% 44.0% 45.6% 44.4% 45.1% 47.1% After-Tax Return on Capital (ROC) Adjusted operating profit (a,c) $ 392 $ 382 $ 352 $ 335 $ 307 $ 311 $ 300 Less: adjusted taxes (a,b) (101) (90) (83) (76) (68) (60) (66) Less: tax benefit on interest expense (10) (11) (10) (10) (10) (11) (11) Add: income from equity investments 1 3 2 4 2 5 4 Net operating profit after-tax (NOPAT) $ 282 $ 284 $ 261 $ 253 $ 231 $ 245 $ 227 Beginning capital $ 7,926 $ 7,740 $ 7,551 $ 7,370 $ 7,373 $ 7,321 $ 7,358 Ending capital $ 7,877 $ 7,926 $ 7,740 $ 7,551 $ 7,370 $ 7,373 $ 7,321 Average capital $ 7,902 $ 7,833 $ 7,646 $ 7,461 $ 7,372 $ 7,347 $ 7,340 ROC % 3.6% 3.6% 3.4% 3.4% 3.1% 3.3% 3.1% ROC % (annualized) 14.3% 14.5% 13.7% 13.6% 12.5% 13.4% 12.4% (a) (b) (c) Reported operating profit and taxes include the effect of expensing stock options while 2005 reported amounts do not. The 2005 operating profit and reported tax amounts have been adjusted to include the pro-forma impact of expensing stock options and are comparable to the presentation. See the following section "2005 FAS 123R Revised," for the calculation of these non-gaap measures. The third quarter 2005 excludes the impact of a $92 million income tax charge for the repatriation of foreign earnings and other tax adjustments. The second quarter includes the impact of a $15 million benefit related to insurance recoveries which increased annualized ROC by 0.5% for that quarter.

10/25/06 15 Earnings Teleconference Non-GAAP Measures, cont. ($MM, except per share data) 2005 SFAS 123R Revised Income Statement Amounts ("Revised") First 2005 Second 2005 2005 Fourth 2005 Reported Adj. (a) Revised Reported Adj. (a) Revised Reported Adj. (a) Revised Reported Adj. (a) Revised Praxair Consolidated: Sales $ 1,827 $ - $ 1,827 $ 1,919 $ - $ 1,919 $ 1,890 $ - $ 1,890 $ 2,020 $ - $ 2,020 Cost of sales 1,109-1,109 1,167-1,167 1,144 (1) 1,145 1,221-1,221 Selling, general and administrative 245 (9) 254 247 (10) 257 243 (9) 252 252 (9) 261 Depreciation and amortization 162-162 163-163 165-165 175-175 Research and development 20-20 19 (1) 20 19-19 22 (1) 23 Other income (expense) - net 18-18 (1) - (1) (2) - (2) (5) - (5) Operating profit 309 (9) 300 322 (11) 311 317 (10) 307 345 (10) 335 Interest expense - net 42-42 41-41 40-40 40-40 Income before income taxes 267 (9) 258 281 (11) 270 277 (10) 267 305 (10) 295 Income taxes 69 (3) 66 64 (4) 60 163 (3) 160 80 (4) 76 198 (6) 192 217 (7) 210 114 (7) 107 225 (6) 219 Minority interests (7) - (7) (13) - (13) (8) - (8) (9) - (9) Income from equity investments 4-4 5-5 2-2 4-4 Income before accounting change 195 (6) 189 209 (7) 202 108 (7) 101 220 (6) 214 Cumulative effect of accounting change - - - - - - - - (6) - (6) Net Income $ 195 $ (6) $ 189 $ 209 $ (7) $ 202 $ 108 $ (7) $ 101 $ 214 $ (6) $ 208 Per share data (b) Basic earnings per share $ 0.60 (0.02) $ 0.58 $ 0.65 (0.02) $ 0.63 $ 0.33 (0.02) $ 0.31 $ 0.68 (0.02) $ 0.66 Diluted earnings per share $ 0.59 (0.02) $ 0.57 $ 0.63 (0.02) $ 0.61 $ 0.33 (0.02) $ 0.31 $ 0.67 (0.02) $ 0.65 Segment Operating Profit: North America $ 166 (5) $ 161 $ 161 (6) $ 155 $ 165 (6) $ 159 $ 193 (6) $ 187 Europe 67 (1) 66 72 (1) 71 63 (1) 62 61 (1) 60 South America 43 (1) 42 51 (2) 49 52 (1) 51 56 (1) 55 Asia 22 (1) 21 24 (1) 23 24 (1) 23 25 (1) 24 Surface Technologies 11 (1) 10 14 (1) 13 13 (1) 12 10 (1) 9 Total $ 309 (9) $ 300 $ 322 (11) $ 311 $ 317 (10) $ 307 $ 345 (10) $ 335 (a) Pro-forma adjustments reflect the impact of expensing stock options and include a change in expense recognition related to full-retirement eligible employees (see Note 1 on page 47 of the 2005 Annual Report.) (b) Calculated on income before accounting change.

10/25/06 16 Earnings Teleconference Non-GAAP Measures, cont. ($MM, except per share data) The Company believes adjusted net income and diluted EPS, quarterly and full-year earnings guidance amounts for, and quarterly effective tax rates, which reflect 2005 results adjusted to include stock option expense and exclude the impact of a third quarter $92 million income tax charge and accounting change, help investors understand underlying performance on a comparable basis. Ended September 30, Full Year 4Q Adjusted Net Income, Diluted EPS 2005 2005 2005 Reported income before accounting change $ 247 $ 108 $ 732 $ 220 Add: income tax charge - 92 92 - Less: proforma stock option expense - (7) $ (26) $ (6) Adjusted Net income $ 247 $ 193 $ 798 $ 214 Diluted weighted average shares 329,498 329,993 329,685 329,113 Reported diluted earnings per share before accounting change $ 0.75 $ 0.33 $ 2.22 $ 0.67 Add back: income tax charge $ - $ 0.28 $ 0.28 $ - Less: proforma stock option expense $ - $ (0.02) $ (0.08) $ (0.02) Adjusted diluted earnings per share $ 0.75 $ 0.59 $ 2.42 $ 0.65 Percentage increase diluted EPS versus 2005 27% Fourth Full Year Adjusted ly and Full Year Diluted EPS Guidance Low end High end Low end High end Reported nine-month diluted EPS $ - $ - $ 2.18 $ 2.18 Expected fourth quarter diluted EPS $ 0.75 $ 0.78 $ 0.75 $ 0.78 $ 0.75 $ 0.78 $ 2.93 $ 2.96 2005 Adjusted diluted earnings per share (above) $ 0.65 $ 0.65 $ 2.42 $ 2.42 Percentage increase 15% 20% 21% 22% Ended September 30, Adjusted ly Effective Tax Rate 2005 Reported income before income tax $ 354 $ 277 Less: divestiture gains (14) - Adjusted income before income tax $ 340 $ 277 Reported income tax expense $ 101 $ 163 Less: 2005 income tax charge - (92) Less: taxes on divestiture gains (11) - Adjusted income tax expense 90 71 Underlying effective tax rate 26.5% 26%